SHIMMER Women Athletes Volume 5 was the fifth SHIMMER event to be recorded by SHIMMER Women Athletes, the event took place on May 21, 2006 at the Berwyn Eagles Club in Berwyn, Illinois. This was the first of two events recorded, the second event being the following volume SHIMMER Women Athletes Volume 6.
- Numbers in parentheses indicate the length of the match.
- Daizee Haze defeated Portia Perez (2:29)
- Rain defeated Lorelei Lee (9:18)
- MsChif defeated Cindy Rogers (7:59)
- Amber O'Neal defeated Serena (8:12)
- Lexie Fyfe & Malia Hosaka defeated Ariel & Josie (11:59)
- Allison Danger defeated Cheerleader Melissa (9:45)
- Amazing Kong defeated Nikki Roxx (10:39)
- Nikita defeated Lacey (14:56)
- Rebecca Knox defeated Daizee Haze in a Best Two Out Of Three Falls Match (28:05)
- Daizee Haze beat Rebecca Knox (17:22)
- Rebecca Knox beat Daizee Haze (23:10)
- Rebecca Knox beat Daizee Haze