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SHIMMER Women Athletes Volume 2 was the twenty-second SHIMMER event to be recorded by SHIMMER Women Athletes, the event took place on October 19, 2008 at the Eagles Club in Berwyn, Illinois. This was the second of two events recorded, the first event being the previous volume SHIMMER Women Athletes Volume 21.
Numbers in parentheses indicate the length of the match.
- Singles Match: Rain defeated Daffney
- Singles Match: Danyah defeated Cat Power
- Singles Match: Amazing Kong defeated Rachel Summerlyn
- Tag Team Match: The Experience (Lexie Fyfe & Malia Hosaka) defeated Pink Ladies (Jessie McKay & Madison Eagles)
- Singles Match: Mercedes Martinez defeated Amber O'Neal
- Singles Match: Cheerleader Melissa defeated Jennifer Blake
- Singles Match: Daizee Haze defeated Miss Natural
- Singles Match: Jetta defeated Nikki Roxx
- SHIMMER Tag Team Championship Match: Ashley Lane & Nevaeh (c) defeated Canadian Ninjas (Nicole Matthews & Portia Perez)
- Singles Match: *LuFisto defeated Wesna Busic
- SHIMMER Championship Match: MsChif (c) defeated Ariel
- Singles Match: Serena Deeb defeated Sara Del Rey